Miners are not incentivised to earn the most money in the next block possible. They are incentivised to maximise their return on investment.

This would be right if you assume that all Bitcoin miners act as a single entity. In that case it is true that that entity's goal is to maximize overall ROI.

But each miner makes decisions on his own. Are you familiar with a concept of Nash equilibrium, prisoner's dilemma, etc?

The fact that nobody is using this kind of a behavior right now doesn't mean that we can rely on it.

For example, Peercoin was horribly broken in 6 months after its release (e.g. people reported that they are able to generate 50 consecutive blocks simply by bringing a cold wallet online) and yet nobody bothered to exploit it, and it managed to acquire non-negligible "market cap".

So we have an empiric evidence that proof-of-stake miners are motivated to keep network secure. So, maybe, we should switch to proof-of-stake, if it was demonstrated that it is secure?

There are good reasons to not switch to proof-of-stake. Particularly, the kind which is used in Peercoin is not game-theoretically sound. So even if it works right now, it can fail in a big way once attackers will really get around to it. An attack requires significant knowledge, effort and, possibly, capital, so it might be only feasible on a certain scale.

So, well, anyway, suppose Peter Todd is the only person interested in maintaining replace-by-fee patches right now, and you can talk him into abandoning them.
OK, perhaps zero-confirmation payments will be de-facto secure for a couple of years. And thus a lot of merchants will rely on zero-confirmation payments protected by nothing but a belief in honest miners, as it is damn convenient.

But, let's say, 5 years from now, some faction of miners who own soon-to-be-obsolete equipment will decide to boost their profits with a replace-by-fee pool and a corresponding wallet. They can market it as "1 of 10 hamburgers are free" if they have 10% of the total hashpower.

So would you take a responsibility for pushing the approach which isn't game-theoretically sound?